HYSYS now allows you to use electrolytes through Aspen Properties. There are a couple of things you need to keep in mind to use this successfully. The key is that HYSYS uses the Apparent mode. Initially I thought, why take this option? Why not take the true approach which doesn't suffer from some of the below issues. It would appear that it is you, the users that have preferred this approach. I was a bit sceptic at first, but a recent visit to hard core Aspen Plus users convinced me that users indeed prefer to juggle with molecules, not with ions.
That being said, on to the practial stuff:
When using apparent mode, you have to make sure that you enter any component that will disappear from the aqueous phase in your initial composition. As an example, if you intend to model a solution of Na2CO3 that will get acidified using for example H2SO4, this will only work properly if you represent the Na2CO3 by NaOH and CO2 in you feed stream. When the conditions are such that the CO2 and NaOH will form dissolved ions, this will be honoured. But, if you add enough H2SO4, the CO2 will go to the vapour phase.
Wednesday, 14 October 2009
Using Electrolytes in HYSYS - Some things are good to know
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Kwizim
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16:09
Labels: Electrolytes, Steady State, Thermodynamics
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Contents By Category
Utility
Thermodynamics
- Did you know series: When using Lee-Kesler Enthalpies with the PR EOS, you get better enthalpies AND ASME steam enthalpies for water as a bonus
- Using Electrolytes in HYSYS
- Using Electrolytes in HYSYS - Some things are good to know
- Modelling TEG Dehydration accurately
- Dealing with thermodynamics: the difference between petroleum industry and chemical industry
- Matching the oil density from PVT analysis with HYSYS results
Dynamic
- Did You Know Series: Manipulating flows in dynamics
- Dynamic Modelling of Flare Networks
- The HYSYS Process Data Tables - The Ugly Duckling
- Modelling Valves in HYSYS Steady State and Dynamics
- Modelling process piping in HYSYS Dynamics
- Use the HYSYS Carry-over capability to unclutter your PFD
- How NOT to specify equipment elevation in dynamic modelling
Steady State
- Did you know series: You can set a component ratio using the balance block
- The HYSYS Process Data Tables - The Ugly Duckling
- Modelling Valves in HYSYS Steady State and Dynamics
- What does "Compressible Flow" mean? Isn't any gas compressible?
- Using Electrolytes in HYSYS - Some things are good to know
- My column initially converges, but with a different feed it fails to converge
- Causes of inconsistencies can be elusive
- Make sure you have an understanding of the complete process when modelling
- Use the HYSYS Carry-over capability to unclutter your PFD
- Don't blame the simulator, at least not right away
- Matching the oil density from PVT analysis with HYSYS results
- Depressuring studies and the HYSYS depressuring utility
- The HYSYS column solver may be able to do more than you think
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